南京太平门地段雪松树年轮及其根土中化学元素含量的相关性研究   总被引：6，自引：0，他引：6  

钱君龙  柯晓康 《地理科学》1998,18(4):374-378

１９９４年在南京市太平门街道采集了五株雪松的年轮样及其根部土壤（黄棕壤ｐＨ＝６．６８）,分别测定了Ｌｉ、Ａｌ、Ｐ、Ｋ、Ｍｎ、Ｃｏ、Ｃｕ、Ｚｎ、Ｃｄ、Ｂａ和Ｐｂ等１１种化学元素含量,实测结果验证了雪松年轮与其根部当年土壤中化学元素含量满足对数线性相关模式;ｌｇＣ′（Ｚ,ｔ）＝ａ（Ｚ）＋ｂ（Ｚ）ｌｇＣ（Ｚ,ｔ）。根据年轮元素含量Ｃ（Ｚ,ｔ）可以重建过去根土中元素含量Ｃ′（Ｚ,ｔ）,即反映环境（土壤）中元素含量的逐年演变的年份序列。利用Ｃ（Ｚ,ｔ）中最低含量可估算该地段黄棕壤的土壤元素背景值。  相似文献   

Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption     

N. J. Pawar  J. B. Pawar  Suyash Kumar  Ashwini Supekar 《Aquatic Geochemistry》2008,14(1):41-71

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.  相似文献   

Laser probe Ar/Ar dating: History and development from a technical perspective     

Hironobu Hyodo   《Gondwana Research》2008,14(4):609

The ⁴⁰Ar/³⁹Ar method using a laser probe opened the door to microscale measurements and diffusion profiles frozen in samples. In the first decade since the initial application of a laser for ⁴⁰Ar/³⁹Ar dating in 1973, practical applications have been few. This is due not only to the fact that the laser and vacuum technologies were immature but that mass spectrometry was also in its infancy. In those days, the sensitivity of a mass spectrometer was generally insufficient to measure the small amount of argon degassed from a geological sample by a laser. These problems have subsequently been solved by new technologies. To understand their current status, a brief history of their development is outlined. This outline focuses on the required detection limit in micro scale measurement, practical approaches for accurate measurement are explained through examples in our laboratory specifically relating to the technical aspects of ⁴⁰Ar/³⁹Ar dating.  相似文献   

黑河中下游荒漠区植物多样性分布对土壤水分变化的响应   总被引：9，自引：0，他引：9  

李新荣  何明珠  贾荣亮 《地球科学进展》2008,23(7):685-691

基于对黑河流域中下游荒漠区植被和土壤生境的调查分析,以土壤水分在各调查样地中的差异来反映研究区的生态水文特征,采用种的丰富度和多度来代表荒漠植物多样性研究了荒漠植物,包括隐花植物多样性分布对土壤水分变化的响应。土壤水分变化不仅直接影响着荒漠植物的多样性,而通过影响其它生境因子又间接地影响着多样性的维持。因此,如何维持中下游相对稳定的土壤水分来源是该区荒漠植物多样性保育今后所要面临的挑战。  相似文献   

生物多样性遥感研究进展   总被引：3，自引：0，他引：3  

魏彦昌  吴炳方  张喜旺  杜鑫 《地球科学进展》2008,23(9):924-931

随着遥感技术和新型传感器的发展,遥感已成为目前区域或全球生物多样性研究的重要方法。综述了目前国内外生物多样性遥感研究的最新进展;分析了遥感生物多样性研究的主要理论基础,包括光谱变异假说、生产力假说和种—面积关系理论等;总结了利用高空间和高光谱分辨率遥感数据直接监测生物物种及其多样性的进展与局限性;基于遥感反演的不同环境变量进行生物多样性模拟和预测是目前最常用的方法,对其进行了较详细的分析,并介绍了相关模型的发展。最后,总结了该方法在我国的应用局限,指出增进学科合作、将遥感方法与生态学理论和模型相结合、重视地面验证数据的使用将是生物多样性遥感研究的发展趋势。  相似文献   

长江流域河水和悬浮物的锂同位素地球化学研究   总被引：9，自引：1，他引：8  

汪齐连  刘丛强  赵志琦  丁虎 《地球科学进展》2008,23(9):952-958

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成（δ⁷Li）分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成（δ⁷Li）变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合：其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。  相似文献   

Plant distribution at the mobile dune scale and its relevance to soil properties and topographic features     

Xiaoan Zuo  Halin Zhao  Xueyong Zhao  Yirui Guo  Yulin Li  Yayong Luo 《Environmental Geology》2008,54(5):1111-1120

A survey was conducted in an 11-year recovery mobile dune (RMD11) and a 20-year recovery mobile dune (RMD20), in Horqin Sandy Land, Northern China, to determine plant distribution at the mobile dune scale and its relevance to soil properties and topographic features. The results showed that (1) vegetation cover and species number increased from dune top to bottom in the restoration process of mobile dune; (2) the average value of soil organic C, total N, pH, relative height of sampling site, very fine sand content and soil water contents (40−60 and 60−80 cm) of RMD11 were less than that of RMD20, respectively, and there were significant differences (P < 0.05) between the two dunes; (3) soil resources were redistributed by shrub restoration and relative height of sampling site on dune. The distribution of sand pioneer plant, Agriophyllum squarrosum, was positively related to the relative height of sampling site and soil water content, while that of other herbaceous plants was positively related to soil nutrients in the restoration process of mobile dune. These results suggest that at mobile dune scale, plant distributions are determined by a combination of soil properties and topographic feature. Much effort should be made to preserve the interdune lowland and to improve the level of soil nutrients on mobile dune.  相似文献   

Distribution of Cd,Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China   总被引：2，自引：0，他引：2  

Ping Du  Nandong Xue  Li Liu  Fasheng Li 《Environmental Geology》2008,55(1):205-213

An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.  相似文献   

Crystal chemical significance of chemical zoning in dissakisite-(Ce)     

Mihoko Hoshino  Mitsuyoshi Kimata  Norimasa Nishida  Masahiro Shimizu 《Physics and Chemistry of Minerals》2008,35(2):59-70

Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types. Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F ₀| > 4σF ₀] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal, where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified as autoepitaxy.  相似文献   

The geochemistry of gem opals as evidence of their origin     

Eloïse Gaillou  Aurlien Delaunay  Benjamin Rondeau  Martine Bouhnik-le-Coz  Emmanuel Fritsch  Guy Cornen  Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.  相似文献